𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Conformational Analysis and Chromic Acid Oxidation. Oxidation Rates and Equilibrium Constants of Epimeric Alcohols

✍ Scribed by Paul Müller; Jean-Claude Perlberger

Publisher
John Wiley and Sons
Year
1976
Tongue
German
Weight
475 KB
Volume
59
Category
Article
ISSN
0018-019X

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The linear free energy relationship of Sicher for relative reactivity towards chromic acid oxidation (ΔΔ__G__) as a function of thermodynamic stability (Δ__G__) has been reexamined with 23 pairs of epimeric alcohols. The plot of Δ__G__ vs. Δ__G__ has a slope of 0.8, a correlation coefficient of 0.97 and a standard deviation of 0.23 kcal/mol on ΔΔ__G__~Ox~. The limitations of the relationship and the exceptions are discussed.

📜 SIMILAR VOLUMES

Steric Effects on Reaction Rates. Rate a
Steric Effects on Reaction Rates. Rate and equilibrium constants for oxidation of cyclanols
✍ Paul Müller; Jacky Blanc 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 German ⚖ 393 KB 👁 2 views

## Abstract Equilibrium constants for oxidations of cyclanols by cyclohexanone in benzene have been determined in the presence of aluminium isopropoxide. The free energies of the equilibrium (Δ__G__~ox~) are correlated with equilibrium constants for dissociation of cyanohydrins, rate constants for

Steric Effects on Reaction Rates – III.
Steric Effects on Reaction Rates – III. Application of Force-Field Calculations to Chromic Acid Oxidation of Alcohols
✍ Paul Müller; Jacky Blanc; Dieter Lenoir 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 German ⚖ 470 KB

## Abstract The rates of oxidation with chromic acid of 15 bi‐ and polycyclic secondary alcohols have been measured and correlated with strain changes calculated by the MM1‐program between the alcohols and the corresponding ketones. A correlation of the same quality is obtained upon representation

Exploration of Rate-Limiting Conformatio
Exploration of Rate-Limiting Conformational State for 5-[(7-Chloro-4-quinolinyl)amino]-3-[(alkylamino)methyl] [1,1′-biphenyl]-2-ols and Nω-Oxides (Tebuquine Analogues) for Antimalarial Activity Using Molecular Shape Analysis and Molecular Field Analysis Studies.
✍ Pooja Sharma; Sandeep Chhabra; Nitin Rai; Nanda Ghoshal 📂 Article 📅 2007 🏛 John Wiley and Sons ⚖ 19 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.