On the relation between three-dimensional and collinear rate constants for vibrational energy transfer

Comments on the linear free-energy corre

Comments on the linear free-energy correlation between O3 and OH addition reactions reported in “rate constants for the gas-phase reactions of O3 with a series of carbonyls at 296 K”

✍ J. S. Gaffney; S. Z. Levine 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 English ⚖ 152 KB

Recently, Atkinson et al. [l] reported measurements on the reaction of ozone with a series of carbonyls. In that study a correlation between ozone addition and hydroxyl-radical addition reactions was employed to predict OH addition coefficients for acrolein and crotonaldehyde of approximately 2 X an