The hydrogen fluoride infrared chemiluminescence produced by the reactions of fluorine atoms with cyclopropane, cyclopentane, and cyclohexane have been studied. The emission data were used to determine the vibrational energy distributions for the abstraction of hydrogen from the secondary carbon-hyd
The effect of vibrational energy on the reaction of molecular hydrogen with atomic oxygen
β Scribed by John H. Birely; Jerome V.V. Kasper; Francis Hai; Lane A. Darnton
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 522 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
An upper bbund of 6 X 10" cm3/mole s on the rate constant for the reaction. of atomic oxygen with vibrntional-I$ excited Yz has been deduced from laboiatory'observations and from detailed computer &ulations.
From this result it can be shown that no more than 30% of the vibrational energy of Hz is effective in overcoming the activation energy for the 0 + Hz reaction:
.. 1. introduction * This work wu conducted.under US Air Force Space and Missile Syitems (SAMSO) Contract No. FO4701-73CaO75.
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