The hydrogen fluoride infrared chemiluminescence produced by the reactions of fluorine atoms with cyclopropane, cyclopentane, and cyclohexane have been studied. The emission data were used to determine the vibrational energy distributions for the abstraction of hydrogen from the secondary carbon-hyd
Electronic and vibrational energy disposal in the reactions of fluorine atoms with hydrogen bromide and hydrogen iodide
โ Scribed by J.P. Sung; D.W. Setser
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 645 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The infrared chcmilumincscenco arising from the hydrogen abstraction reactions of ELuorinc atoms with 1120, H2S. Ii202 snd CH4 was investignted et low pressure in n ilow apparatus. Emission was found only from the HF product. The rclotive RF vibrational populations were determined under conditions w
The rotational and vibrational energy distributions of S2(a 1~ and X 3y.~-) generated in the reaction ofS(3p 4, 1D) with thiirane C2H4S are measured, using the laser-induced fluorescence technique. Nascent energy distributions are approximated by Boltzmann distributions with rotational and vibration
The vibrational energy relaxation (VER) of polyatomic molecules has been the central issue in many of the chemical reactions in condensed phase [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15][16][17] as well as in gas phase . The vibrational energy introduced to the molecule is immediately redis
The mechanism of the reaction between H and CHrNOt, has been studied in a discharge flow system using electron paramagnetic resonance and modulated molecular beam mass spectrometry for the detection of reactants and products. Deuterium atoms have, in addition to CDfiOr, been used to support the prop