✦ LIBER ✦

Primary processes and energy disposal in the reaction of S(1D) atoms with thiirane

✍ Scribed by Masafumi Ohashi; Zhen Song; Yutaka Matsumi; Masahiro Kawasaki

Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 404 KB
Volume: 220
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(94)00144-8

No coin nor oath required. For personal study only.

✦ Synopsis

The rotational and vibrational energy distributions of S2(a 1~ and X 3y.~-) generated in the reaction ofS(3p 4, 1D) with thiirane C2H4S are measured, using the laser-induced fluorescence technique. Nascent energy distributions are approximated by Boltzmann distributions with rotational and vibrational temperatures: Trot = 3000--500 K and T,~b= 6000 K for $2 (a 1~,); Tot i> 4000 K and T~b = 1200 K for $2 (X 3Z~-). Relative product branching ratios from S (~D) + C2H4S under thermal collision conditions are estimated to be 0.14/0.30/0.56 for S2(a t~)/S2(X 3Z~-)/S(3p).

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