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Vibrational and rotational energy disposal in the H + D2 reaction at 1.3 eV: Surprisal analysis of experiments and computations

✍ Scribed by E. Zamir; R.D. Levine; R.B. Bernstein

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
371 KB
Volume
107
Category
Article
ISSN
0009-2614

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✦ Synopsis

Recent independent experimental determinations. by Za.re and Valentini and their co-workers, of the HD product state distribution are consistent with a common set of surprkal parameters: h, = 2 and 0R in the range 3-5. Analysis of rhe computational results of Blais and Trublar su,, ~oests that a some\vhsr larger fraction of the avatible energy is channeled into rotation and that theorientatiofl of the emergent HD molecules is constrained.

' For previousappliutions. see ref.

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