✦ LIBER ✦

Initial internal energy distributions of ZnH (ZnD) produced in the reaction of Zn(4s4p3P1) with H2, D2, and HD

✍ Scribed by W.H. Breckenridge; Jiang-Hua Wang

Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 632 KB
Volume: 123
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(86)87005-1

No coin nor oath required. For personal study only.

✦ Synopsis

Initial rotational (and for the H, reaction, vibrational) quantum-state distributions of ZnH (ZnD) formed in the exoergic reactions of Zn( ) with H,, D,, and HD were determined. Unusual isotope effects are observed, and is postulated that product rotational energy is a result of an angular dependence of the exit-channel potential in the decomposition of H-Zn-H, H-Zn-D, and D-Zn-D insertion intermediates.

📜 SIMILAR VOLUMES

Initial internal energy distributions of

Initial internal energy distributions of CdH (CdD) produced in the reaction of Cd(5s5p3P1) with H2, D2, and HD

✍ W.H. Breckenridge; H. Umemoto; Jiang-Hua Wang 📂 Article 📅 1986 🏛 Elsevier Science 🌐 English ⚖ 479 KB

Nascent rotational state distributions o

Nascent rotational state distributions of ZnH (X 2Σ+) produced in the reactions of Zn (4 1P1) with simple alkane hydrocarbons

✍ Hironobu Umemoto; Tohru Sato; Kazuto Takano; Shigeru Tsunashima; Kazuya Kuwahara 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 457 KB

The reactions of Zn(4 'PI) with CH,, C H C H and C( CHs), were studied by employing a laser pump-and-probe technique. 2 6, 3 B The nascent rotational state distributions of ZnH(X %+, v" =O) were determined. The rotational distributions could be approximated by Boltzmann distributions in all cases.

Dynamics of the reactions of Mg(3s3p1p1)

Dynamics of the reactions of Mg(3s3p1p1) with H2, HD, and D2: Rotational quantum state distributions of MgH (MgD) products

✍ W.H. Breckenridge; Jiang-Hua Wang 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 625 KB

The initial bimodal distributions of product MgH( u=O) rotational states in the reaction of Mg( 'P, ) with H2 or HD are found to be identical. Similar results were found for MgD( v=O) produced from D2 or HD. From these as well as other recent results, it is proposed that both the predominant "high-N

Px ligands with a maximum of electron-do

Px ligands with a maximum of electron-donating ability: VI. [CoCp“(η4-P4){Cr(CO)5}3] (Cp” η5-C5H3tBu2-1,3), the product of the reaction between P4 and [CoCP“(μ-CO)]2 in the presence of [Cr(CO)5THF]

✍ Manfred Scheer; Uta Becker; John C. Huffman; Malcolm H. Chisholm 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 273 KB

Stereoselective reaction of ±-7-Phenyldi

Stereoselective reaction of ±-7-Phenyldinaphtho[2,1-b;1′,2′-d]phosphole with an optically active palladium complex. Molecular structure and fluxional behavior of Pd(S)- C6H4CH(CH3)N(CH3)2(P)-PPh(C20H12) Cl

✍ Kazuhide Tani; Hironori Tashiro; Miho Yoshida; Tsuneaki Yamagata 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 813 KB

X-ray crystal structures of 1,2,4-tri-O-

X-ray crystal structures of 1,2,4-tri-O-acetyl-5-deoxy-3-O-methyl-5-[(S)-phenylphosphinyl]-α-d-xylopyranose and its 5-[(S-phenylphosphinothioyl] derivative, and conformations of d-xylopyranose analogs having a C6H5P(R) group in the hemiacetal ring

✍ Thomas Richter; Peter Luger; Tadashi Hanaya; Hiroshi Yamamoto 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 780 KB

X-ray crystallographic analyses are reported for the two title compounds (8 and 9), of which the former crystallized in two modifications (8n and 8b). In all three structures, the pyranose rings have the %, (D) conformation and the substituents at C-l are axial and those at C-24-4 are equatorial. Th