Electronic branching ratios in the chemiluminescent reactions of Sr(1S) and Sr∗(3P, 1D) atoms with ICl and IBr
✍ Scribed by P. Kierzkowski; B. Pranszke; A. Kowalski
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 419 KB
- Volume
- 254
- Category
- Article
- ISSN
- 0009-2614
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## Abstract Time‐resolved investigations of the atomic resonance fluorescence Sr(5^3^P~1~ → 5^1^S~0~) and the molecular chemiluminescence from SrCl(A^2^Π~1/2,3/2~, B^2^Σ^+^ → X^2^Σ^+^) are reported following the reaction of the electronically excited strontium atom, Sr(5s5p(^3^P~J~)), 1.807 eV abov
Initial rotational (and for the H, reaction, vibrational) quantum-state distributions of ZnH (ZnD) formed in the exoergic reactions of Zn( ) with H,, D,, and HD were determined. Unusual isotope effects are observed, and is postulated that product rotational energy is a result of an angular dependenc