✦ LIBER ✦

The reaction of atomic oxygen and hydrogen with nitric acid

✍ Scribed by C. J. Chapman; R. P. Wayne

Publisher: John Wiley and Sons
Year: 1974
Tongue: English
Weight: 627 KB
Volume: 6
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550060502

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✦ Synopsis

Abstract

The reactions

have been studied in a discharge‐flow system. Kinetic studies were made using resonance fluorescence for the measurement of atom concentrations. Based on the rates of atom loss, the following upper limits were obtained for the rate constants:

Observed reaction in the HHNO~3~ system is at least partially due to an autocatalytic chain removal of both reactants. Diagnostic tests have suggested that OH, NO~2~, and NO~3~ are the chain carriers.

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