The diastereoselective reduction of a range of acyclic Bhydroxy ketones with triacetoxyborohydride is described. In all cases, the anti 1,3-dial diastereomer is the principal product (eq I).
✦ LIBER ✦
The directed reduction of β-hydroxy ketones employing Me4NHB(OAc)3
✍ Scribed by David A. Evans; Kevin T. Chapman
- Book ID
- 104227593
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- French
- Weight
- 27 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Page 5939, paragraph 2, sentence 3 should read: The stereochemical information gained from these cases is consistent with a hydroxyl-mediated reduction, a mechanistic postulate first suggested by Saksena.Sa 5. (a) Saksena, A.
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
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