The crystal structure of tetragonal nickel(ii)-hydrogen-(1)-malate tetra hydrate
โ Scribed by W. van Havere; A. T. H. Lenstra
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 159 KB
- Volume
- 89
- Category
- Article
- ISSN
- 0037-9646
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Racemic manganese(I1) (+)-1-malate t r i h y d r a t e c r y s t a l i z e s i n the space group Pcab, w i t h Z = 8 and a = 14.201(8), b = 14.656(4), c = 8.265(5)a. The Mn-ion i s surrounded by s i x oxygen atoms forming an octahedron, s l i g h t l y d i s t o r t e d by the r i g i d i t y o f o
Complexes of Ni II , Cu II , Zn II , and Co III containing the 1,2,6,7tetracyano-3,5-dihydro-3,5-diiminopyrrolizinide (L) and the 2,4-tert-butylacetylacetonide (DPM) ligands have been synthesized and characterized. The absorption optical spectra of these species and of the corresponding ML 2 complex