The Crystal Structure of Monoclinic Copper(II)-hydrogen-(1)-Malate Dihydrate
β Scribed by W. van Havere; A. T. H. Lenstra
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 216 KB
- Volume
- 87
- Category
- Article
- ISSN
- 0037-9646
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Racemic manganese(I1) (+)-1-malate t r i h y d r a t e c r y s t a l i z e s i n the space group Pcab, w i t h Z = 8 and a = 14.201(8), b = 14.656(4), c = 8.265(5)a. The Mn-ion i s surrounded by s i x oxygen atoms forming an octahedron, s l i g h t l y d i s t o r t e d by the r i g i d i t y o f o
The title compound (C 27 H 27 CuN 5 OS ) crystallizes in the orthorhombic space group Pbca with a = 11.1865(3)Γ , b = 13.2006(3)Γ , c = 34. 2304(1)Γ , V = 5054.75(2)Γ 3 , Z = 8, D cal = 1.401 Mg/m 3 at T = 293 K. The structure was solved by direct methods and refined by full-matrix least-squares proced