The Conversion of Saturated Hydrocarbons into Carboxylic Acids Using Fe(CO)5-H2O2 Oxidation. -Hydrocarbons such as cyclohexane or adamantane are transformed predominantly to homologous acids such as (I) and (II) with Fe(CO)5 and H2O2 in pyridine/HOAc. -(BARTON, D. H. R.;
The conversion of saturated hydrocarbons into carboxylic acids using Fe(CO)5H2O2 oxidation
✍ Scribed by Derek H.R. Barton; Nathalie C. Delanghe
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- French
- Weight
- 271 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Oxidation by a "H2O2-Vanadium Complex-Pyrazine-2-carboxylic Acid" Reagent. Part 5. Oxidation of Lower Alkanes into Carbonyl Compounds. -Oxidation of lower alkanes by the title reagent system in MeCN provides, in general, predominantly or exclusively carbonyl compounds. Scope and limitations as well
## Abstract A wide variety of aldehydes were efficiently converted to their corresponding carboxylic acids in high yields using H~2~O~2~/HCl in the presence of hydroxylamine hydrochloride. In addition, selective oxidation of aldehydes in the presence of other functional groups such as hydroxyl grou