ChemInform Abstract: The Conversion of Saturated Hydrocarbons into Carboxylic Acids Using Fe(CO)5-H2O2 Oxidation.
β Scribed by D. H. R. BARTON; N. C. DELANGHE
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 28 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
The Conversion of Saturated Hydrocarbons into Carboxylic Acids Using Fe(CO)5-H2O2 Oxidation. -Hydrocarbons such as cyclohexane or adamantane are transformed predominantly to homologous acids such as (I) and (II) with Fe(CO)5 and H2O2 in pyridine/HOAc. -(BARTON, D. H. R.;
π SIMILAR VOLUMES
Oxidation by a "H2O2-Vanadium Complex-Pyrazine-2-carboxylic Acid" Reagent. Part 5. Oxidation of Lower Alkanes into Carbonyl Compounds. -Oxidation of lower alkanes by the title reagent system in MeCN provides, in general, predominantly or exclusively carbonyl compounds. Scope and limitations as well