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Oxidative cleavage of the FeFe bond in [C5Me5Fe(CO)2]2 using ferrocinium ion: A facile route to the synthetically useful complexes [C5Me5Fe(CO)2(solvent)]+

✍ Scribed by Daniel Catheline; Didier Astruc

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
265 KB
Volume
266
Category
Article
ISSN
0022-328X

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Cleavage of the Fe–Fe Bond of (Me2SiSiMe
Cleavage of the Fe–Fe Bond of (Me2SiSiMe2)[η5-C5H4Fe (CO)2]2 with Na/Hg and Molecular Structure of the Ring-Opened Complex
✍ Hud-Lin Sun; Zhen-Sheng Zhang; Xiu-Zhong Zhou 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 327 KB 👁 1 views

## Abstract The reaction of the title cyclic complex (1) with sodium amalgam in THF resulted in the expected cleavage of the Fe—Fe bond to afford bis‐sodium salt (Me~2~SiSiMe~2~) [η^5^‐C~5~H~4~Fe (CO)~2~Na]~2~ (4). The latter was not isolated and was used directly to react with MeI, PhCH~2~Cl, CH~3