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Simple Synthesis of [C5H5Fe(CO)dppe]+ and its Photochemical Conversion into the Dinitrogen Complex [{C5H5Fe(dppe)}2N2]2+[1]

โœ Scribed by Priv.-Doz. Dr. Dieter Sellmann; Dipl.-Chem. Ernst Kleinschmidt

Publisher
John Wiley and Sons
Year
1975
Tongue
English
Weight
122 KB
Volume
14
Category
Article
ISSN
0044-8249

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40ยฐC. Slow warm-up to room temperature, column chromatographic work-up (silica gel flash chromatography, elution with a 10 : 1 : 1 mixture of dichloromethane, petroleum ether (30-50ยฐC) and diethyl ether), and Kugelrohr distillation (bath temperature 45 "C at 0.1 torr) afforded the a-methylene-p-lact