𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis and Molecular Structure of the Diphosphaarsirane [{[(η5-C5Me5)(CO)2Fe]P}2AsC66H2tBu3]

✍ Scribed by Prof. Dr. Lothar Weber; Dipl.-Chem. Dagmar Bungardt; Uwe Sonnenberg; Dr. Roland Boese

Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
389 KB
Volume
27
Category
Article
ISSN
0044-8249

No coin nor oath required. For personal study only.

✦ Synopsis

40°C. Slow warm-up to room temperature, column chromatographic work-up (silica gel flash chromatography, elution with a 10 : 1 : 1 mixture of dichloromethane, petroleum ether (30-50°C) and diethyl ether), and Kugelrohr distillation (bath temperature 45 "C at 0.1 torr) afforded the a-methylene-p-lactones 9a-c in 27, 48 and 40% yields, re-

📜 SIMILAR VOLUMES

Synthese und Molekülstruktur des Diphosp
Synthese und Molekülstruktur des Diphosphaarsirans [{[(η5-C5Me5)(CO)2Fe]P}2As C6H2tBu3]
✍ Prof. Dr. Lothar Weber; Dagmar Bungardt; Uwe Sonnenberg; Dr. Roland Boese 📂 Article 📅 1988 🏛 John Wiley and Sons 🌐 English ⚖ 216 KB

Cycloaddukten. Bei hoherer Temperatur (ca. 60°C) polymerisieren die a-Methylen-p-lactone 9 . Wegen der hohen Gentoxizitat der analogen a-Methylen-y-butyrolactone, die Bestandteile zahlreicher Naturstoffe mit sehr unterschiedlichen biologischen Wirkungen sindI6l, sollten die cancerogenen Eigenschafte

Reactivity of Ferriophosphaalkene [(η5-C
Reactivity of Ferriophosphaalkene [(η5-C5Me5)(CO)2Fe–P=C(NMe2)2] and Ferrioarsaalkene [(η5-C5Me5)(CO)2Fe–As=C(NMe2)2] Towards Trimethylaluminium, -gallium and -indium
✍ Lothar Weber; Matthias H. Scheffer; Hans-Georg Stammler; Anja Stammler 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 308 KB

Reaction of equimolar amounts of the ferriophosphaalkene P; M = Al (2a), Ga (3a), In (4a) and E = As; M = Al (2b), Ga (3b), and In (4b). These compounds feature η 1 -coordination [(η 5 -C 5 Me 5 )(CO) 2 FeP=C(NMe 2 ) 2 ] (1a) or the ferrioarsaalkene [(η 5 -C 5 Me 5 )(CO) 2 FeAs=C(NMe 2 ) 2 ] (1b) wi

Molecular Structure of [η-C5H5(CO)2ReC(C
Molecular Structure of [η-C5H5(CO)2ReC(C6H5)P(CH3)3][BCl4]
✍ Dr. Fritz R. Kreissl; Dipl.-Chem. Peter Friedrich 📂 Article 📅 1977 🏛 John Wiley and Sons 🌐 English ⚖ 215 KB

The crystallographic dataC3] and the molecular dimensions of ( 4 ) and ( ) are almost identical. We thus have one of those rare cases in which analyses and spectraL4] are more significant in identifying the compounds than structure determination. The most important structural characteristic of ( 4 )