Synthesis and Structure of the Co3Ti2 Complex [{μ3-[(C5H5)2TiOC]}2{(C5H5)3Co3}]: CO Reduction by Two Different Metal Centers
✍ Scribed by Dr. Sandro Gambarotta; Sergio Stella; Prof. Dr. Carlo Floriani; Dr. Angiola Chiesi-Villa; Dr. Carlo Guastini
- Publisher
- John Wiley and Sons
- Year
- 1986
- Tongue
- English
- Weight
- 253 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0044-8249
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The anionic clusters [Fe 5 MN(CO) 14 Cp] 2-[M = Mo (1) or W (2)] were synthesized from [Fe 4 N(CO) 12 ] -and [MCp(CO) 3 ] - in refluxing acetonitrile. The clusters [Fe 3 M 3 N(CO) 18 ] 3-[M = Mo (3) or W (4)] were prepared by reaction of [Fe 4 N(CO) 12 ] - with [M 2 (CO) 10 ] 2-under the same condit
by the molecular weight (determined cryoscopically in benzene) and the mass spectrum, ( ) is monomeric. The assignment of the substituents at the As=C double bond can be determined only by an X-ray structure analysis. Studies on models suggest the presence of Z isomers in which the aryl and the tri