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The conformation of pentaazamacrocyclics. I. Crystal structures of nickel (II) and copper (II) complexes of 1,4,7,11,14-pentaazacycloheptadecane

โœ Scribed by Jan C. A. Boeyens; Susan M. Dobson; Ebeth-Louise Oosthuizen


Publisher
Springer
Year
1990
Tongue
English
Weight
380 KB
Volume
20
Category
Article
ISSN
1572-8854

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Three new metal complexes, Cu(4-Hcba) 2 (4-cba) 2 (Py) 2 (4-HcbaZ4-cyanobenzoic acid) 1 and M[H(4-cba) 2 ] 2 (Py) 2 (MZNi 2, Co 3), have been prepared by the treatment of 4-Hcba with the respective metal nitrate M(NO 3 ) 2 (MZCu, Ni, Co) in the presence of pyridine (Py). Single-crystal X-ray diffrac