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The chemistry of nickel(II) complexes of 1,4,7,11-tetra-azacyclotetradecane (isocyclam)

✍ Scribed by Robert W Hay; Brian Kinsman; Caroline I Smith


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
374 KB
Volume
14
Category
Article
ISSN
0277-5387

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Kinetics and mechanism of acid-catalyzed
✍ T.P. Dasgupta πŸ“‚ Article πŸ“… 1976 πŸ› Elsevier Science 🌐 English βš– 321 KB

The acid-catalyzed aquation of the title compound has been studied over the range of O.O5<[H+]<OSM and 40" <T<50" C at I=O.5 M. The pseudo-first-order rate constants are directly proportional to [H+] for the range of acidity studied. The results have been interpreted in terms of mechanism involving