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Kinetic and equilibrium studies of the acid dissociation of the copper(II) and nickel(II) complexes of 5,7-dioxo-1,4,8,11-tetra-azacyclotetradecane

โœ Scribed by Robert W. Hay; Mansour M. Hassan


Publisher
Springer
Year
1994
Tongue
English
Weight
548 KB
Volume
19
Category
Article
ISSN
0340-4285

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Kinetics and mechanism of acid-catalyzed
โœ T.P. Dasgupta ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 321 KB

The acid-catalyzed aquation of the title compound has been studied over the range of O.O5<[H+]<OSM and 40" <T<50" C at I=O.5 M. The pseudo-first-order rate constants are directly proportional to [H+] for the range of acidity studied. The results have been interpreted in terms of mechanism involving