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Copper(II) and nickel(II) complexes of hexacyclen (1,4,7,10,13,16-hexa-azacyclo-octadecane) and the kinetics of dissociation of the copper(II) and nickel(II) complexes in acidic solution

✍ Scribed by Robert W. Hay; M. Tofazzal; H. Tarafder; Mansour M. Hassan


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
519 KB
Volume
15
Category
Article
ISSN
0277-5387

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## Abstract The acidity of malondialdehyde as well as the stability of its 1 :1‐complexes with Ni^II^ and Cu^II^ have been determined (Table). In comparison with the enolates of aliphatic β‐dike‐tones the anion C~3~H~3~O~2~βˆ’ has not only a strikingly reduced basicity, but is also a grossly inferior