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The Acidity of Malondialdehyde and the Stability of its Complexes with Nickel(II) and Copper(II)

✍ Scribed by M. M. Osman

Publisher
John Wiley and Sons
Year
1972
Tongue
German
Weight
327 KB
Volume
55
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

The acidity of malondialdehyde as well as the stability of its 1 :1‐complexes with Ni^II^ and Cu^II^ have been determined (Table). In comparison with the enolates of aliphatic β‐dike‐tones the anion C~3~H~3~O~2~βˆ’ has not only a strikingly reduced basicity, but is also a grossly inferior ligand for metal cations.

πŸ“œ SIMILAR VOLUMES

Acidity Constants of the Thienyl- and Ph
Acidity Constants of the Thienyl- and Phenyl-Pyridines and Stability Constants of the Corresponding Copper (II) 1:1 Complexes
✍ Helmut Sigel; Hans Wynberg; T. J. van Bergen; Klaus Kahmann πŸ“‚ Article πŸ“… 1972 πŸ› John Wiley and Sons 🌐 German βš– 254 KB

## Abstract The acidity constants of the six thienyl‐ and the three phenyl‐pyridines, and the stability constants of the corresponding Cu^2+^ 1:1 complexes were determined in aqueous solution (__I__ = 0.1, NaCIO~4~; 25Β°). The basicity of the pyridyl group is increased by a shift of a thienyl or phe