THE CLEMMENSEN AND WOLFF-KISHNER REDUCTIONS OF DIMETHYLKETENE DIMER
β Scribed by HERZOG, HERSHEL L.; BUCHMAN, EDWIN R.
- Book ID
- 118736456
- Publisher
- American Chemical Society
- Year
- 1951
- Tongue
- English
- Weight
- 380 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
Although hydrogenolysis of conjugated (i.e., allylic or bentylic) alcohols or ketones is a well known reaction (l), the hydrogenolysis of the unconjugated carbonyl group '(e.g., I -c II) is not a recognized synthetic procedure (2). We wish to report some results, summarized in the Table, which sugge
Wolff-KishneG carbmyl; tiuctiolc anionic cyclizalion; free rxlical cyclization Abstnact: The observation lhar Wo@Kishner reduction o/a &e-waturated ketone leads to the Irons cyclized product supports the proposed intermediacy of a m&anion in rhis reaction.