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On the mechanism of the Wolff-Kishner reduction

✍ Scribed by Douglass F. Taber; Shawn J. Stachel

Publisher
Elsevier Science
Year
1992
Tongue
French
Weight
198 KB
Volume
33
Category
Article
ISSN
0040-4039

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✦ Synopsis

Wolff-KishneG carbmyl; tiuctiolc anionic cyclizalion; free rxlical cyclization Abstnact: The observation lhar Wo@Kishner reduction o/a &e-waturated ketone leads to the Irons cyclized product supports the proposed intermediacy of a m&anion in rhis reaction.

πŸ“œ SIMILAR VOLUMES

The cleavage of two carbon-carbon bonds
The cleavage of two carbon-carbon bonds in a Wolff-Kishner reduction
✍ Robert P. Lemieux; Peter Beak πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 French βš– 188 KB

The reaction of dispiro[cyclopropane-l,l'-indan-3',1"-cyclopropane]-2'-one (1) under Wolff-Kishner conditions gives spiro[cyclopropane-l,l'-indan] (2) in which the ketone has been reduced and two bonds of one cyclopropane ring have been cleaved. The Wolff-Kishner reaction is a classic method for