✦ LIBER ✦
Catalytic hydrogenolysis as an alternative to the wolff-kishner or clemmensen reduction methods for azabicyclic ketones
✍ Scribed by Louis P. Reiff; Herbert S. Aaron
- Book ID
- 104223963
- Publisher
- Elsevier Science
- Year
- 1967
- Tongue
- French
- Weight
- 161 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
Although hydrogenolysis of conjugated (i.e., allylic or bentylic) alcohols or ketones is a well known reaction (l), the hydrogenolysis of the unconjugated carbonyl group '(e.g., I -c II) is not a recognized synthetic procedure (2). We wish to report some results, summarized in the Table, which suggest that hydrogenolysis over platinum in acid may be a useful general