The chlorine atom sensitized oxidation of HCCl3, HCF2Cl and HCF3
β Scribed by Eugenio Sanhueza
- Publisher
- Elsevier Science
- Year
- 1977
- Weight
- 589 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0047-2670
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## Abstract Smog chamber/FTIR techniques were used to measure __k__(Cl + HCF~2~OCF~2~OCF~2~βCF~2~OCF~2~H) = __k__(Cl + HCF~2~O(CF~2~O)~__n__~(CF~2~CF~2~O)~__m__~CF~2~H) = (5.0 Β± 1.4) Γ 10^β17^ cm^3^ molecule^β1^ s^β1^ in 700 Torr of N~2~/O~2~ diluent at 296 Β± 1 K. The Clβinitiated atmospheric oxida
The C1 atom-initiated oxidation of CHzClz and CH3Cl was studied using the FTIR method in the photolysis of mixtures typically containing Clz and the chlorinated methanes at 1 torr each in 700 torr air. The results obtained from product analysis were in general agreement with those reported by Sanhue