## Abstract Smog chamber/FTIR techniques were used to measure __k__(Cl + HCF~2~OCF~2~OCF~2~‐CF~2~OCF~2~H) = __k__(Cl + HCF~2~O(CF~2~O)~__n__~(CF~2~CF~2~O)~__m__~CF~2~H) = (5.0 ± 1.4) × 10^−17^ cm^3^ molecule^−1^ s^−1^ in 700 Torr of N~2~/O~2~ diluent at 296 ± 1 K. The Cl‐initiated atmospheric oxida
Atmospheric Chemistry of HCF2O(CF2CF2O)xCF2H (x=2–4): Kinetics and Mechanisms of the Chlorine-Atom-Initiated Oxidation
✍ Scribed by Dr. Mads P. Sulbaek Andersen; Vibeke F. Andersen; Prof. Dr. Ole J. Nielsen; Dr. Stanley P. Sander; Dr. Timothy J. Wallington
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 227 KB
- Volume
- 11
- Category
- Article
- ISSN
- 1439-4235
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract Using a relative rate technique the reactions of fluorine and chlorine atoms with CF~3~COOH have been determined to proceed with rate constants of (5.6 ± 0.7) × 10^−11^ and <1 × 10^−17^ cm^3^ molecule^−1^ s^−1^, respectively. Quoted errors for the F atom rate constant reflect statistica
The barium perfluoroalkanedisulfonates Ba(O 3 S) 2 (CF 2 ) n (n = 1, 3±5) and the new potassium fluoroalkanedisulfonates K 2 (O 3 S) 2 CHF, K 2 (O 3 S) 2 CF 2 , and K 2 (O 3 S) 2 (CF 2 ) 5 have been prepared by reaction of (CF 2 ) n (SO 2 F) 2 (n = 1, 3±5) or CHF(SO 2 F) 2 with CaO (or Ca(OH) 2 ) an
The thermal addition of CF,0sCF3(T 1 to CF2CCl2(E) has been investigated between 49.6 and 69.5"C. The initial pressure of CFJ03CF3 was varied between 7 and 240 torr and that of CF2CC12 between 4 and 600 torr. Four products of formula CF30(E),00CF3, wherej = 1 + 4 are formed. The sum of the products
The kinetics and mechanisms of the oxidative degradation of 2,4-dihydroxybenzoic acid (2,4-DHBA) by the Fenton and photo-Fenton processes were investigated in detail by a combination of HPLC, IC, and TOC analyses. The formation of 2,3,4-trihydroxybenzoic acid (2,3,4-THBA) at an early oxidation stage