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An FTIR study of the Cl atom-initiated oxidation of CH2Cl2 and CH3Cl

✍ Scribed by H. Niki; P. D. Maker; C. M. Savage; L. P. Breitenbach

Publisher: John Wiley and Sons
Year: 1980
Tongue: English
Weight: 569 KB
Volume: 12
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550121209

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✦ Synopsis

The C1 atom-initiated oxidation of CHzClz and CH3Cl was studied using the FTIR method in the photolysis of mixtures typically containing Clz and the chlorinated methanes at 1 torr each in 700 torr air. The results obtained from product analysis were in general agreement with those reported by Sanhueza and Heicklen. The relative rate constant for the C1 atom reactions of CHzClz and CH&l was determined to be k(C1+ CH&l)/k(Cl+ CHzClz) = 1.31 f 0.14 (2a) at 298 f 2 K.

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