𝔖 Bobbio Scriptorium
✦   LIBER   ✦

ESR study of the CH2Cl radical in a single crystal of CH3Cl

✍ Scribed by J.P. Michaut; J. Roncin


Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
257 KB
Volume
12
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


An FTIR study of the Cl atom-initiated o
✍ H. Niki; P. D. Maker; C. M. Savage; L. P. Breitenbach πŸ“‚ Article πŸ“… 1980 πŸ› John Wiley and Sons 🌐 English βš– 569 KB

The C1 atom-initiated oxidation of CHzClz and CH3Cl was studied using the FTIR method in the photolysis of mixtures typically containing Clz and the chlorinated methanes at 1 torr each in 700 torr air. The results obtained from product analysis were in general agreement with those reported by Sanhue

Bond dissociation energies and radical h
✍ E. Tschuikow-Roux; S. Paddison πŸ“‚ Article πŸ“… 1987 πŸ› John Wiley and Sons 🌐 English βš– 595 KB

An analysis of thermochemical and kinetic data on the bromination of the halomethanes CH, ,X,, (X = F, C1, Br; n = 1-31, the two chlorofluoromethanes, CH,FCI and CHFCl,, and CH,, shaws that the recently reported heats of formation of the radicals CH2C1, CHClz, CHBr2, and CFC12, and the C-H bond diss

Hydrogen abstraction reactions of OH rad
✍ Li Wang; Yanjie Li; Hongqing He; Jinglai Zhang πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons 🌐 English βš– 831 KB

The hydrogen abstraction reactions of OH radicals with CH₃CHβ‚‚CHβ‚‚Cl and CH₃CHClCH₃ (R2) have been investigated theoretically by a dual-level direct dynamics method. The optimized geometries and frequencies of the stationary points are calculated at the B3LYP/6-311G(d,p) level. To improve the reaction

13C hyperfine coupling and structure of
✍ Anders Lund; Yuhei Shimoyama πŸ“‚ Article πŸ“… 1976 πŸ› Elsevier Science 🌐 English βš– 321 KB

Measurement of the 13C hyperfine coupling constant of -CHC12 in singe crystal CH2C& at 77 K leads to the Lonclusion that the radical converts between two equivalent pyramidal structures at a rate s@ifiuntly higher than 10' Hz. The anisotropy of the g-factor and the I H, 35C1 and 13C hyperfime coupli

Calculation of 13C shielding of the isot
✍ W. T. Raynes; M. Nightingale πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 408 KB πŸ‘ 1 views

The I3C shielding of the isotopomers CH,Cl, CH,DCl, CHD,Cl, and CD,C1 has been calculated for a range of temperatures from an self-consistent field (SCF) shielding surface computed by Buckingham and Olegario. It is found that each successive deuterium substitution increases the shielding by about 0.

ESR spectra and structure of the (CH3)2A
✍ Akinori Hasegawa; Michiro Hayashi πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 English βš– 351 KB

Atter e\posurr: to 7 ra)s~t 77 Ii (C113)2Al\ (Y = Cl, Br,or I) In soled solutton\ of tctrnmeth~Is~l~nc aavc six-lmc CSR ,pcctra \\~th a large II) perfine couplmg ChrlrrlCtcrlhtlc 01 '741 Jnd an JddtttonJl hJogcn sphttmg The results mdlcdte the tormatlon 01 (CH-J)~AIX-\i itll pvramtddl structure The