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The chemistry of the SiH bond with acid treated clays

✍ Scribed by Larry N. Lewis; Donald S. Johnson; Jonathan D. Rich


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
365 KB
Volume
448
Category
Article
ISSN
0022-328X

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Kinetic investigations on the insertion of metal-carbenoid intermediates into the Si-H bond have been carried out. A kinetic isotope effect of 1.5 was found and the plot of log kx/krt vs cr for the reaction of arylsilanes with EDA, gave a straight line with p =-0.31. It was thus concluded that the i