Mechanism of metal-carbenoid insertion i
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Yannick Landais; Liliana Parra-Rapado; Denis Planchenault; Valéry Weber
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Article
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1997
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Elsevier Science
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French
⚖ 286 KB
Kinetic investigations on the insertion of metal-carbenoid intermediates into the Si-H bond have been carried out. A kinetic isotope effect of 1.5 was found and the plot of log kx/krt vs cr for the reaction of arylsilanes with EDA, gave a straight line with p =-0.31. It was thus concluded that the i