✦ LIBER ✦

Difluorocarbene insertion into SiH bonds: the preparation and properties of difluoromethylsilanes

✍ Scribed by H. Bürger; R. Eujen; P. Moritz

Publisher: Elsevier Science
Year: 1991
Tongue: English
Weight: 825 KB
Volume: 401
Category: Article
ISSN: 0022-328X
DOI: 10.1016/0022-328x(91)86223-d

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Asymmetric rhodium carbenoid insertion i

Asymmetric rhodium carbenoid insertion into the SiH bond

✍ Richard T. Buck; Michael P. Doyle; Martin J. Drysdale; Leigh Ferris; David C. Fo 📂 Article 📅 1996 🏛 Elsevier Science 🌐 French ⚖ 248 KB

Mechanism of metal-carbenoid insertion i

Mechanism of metal-carbenoid insertion into the SiH bond

✍ Yannick Landais; Liliana Parra-Rapado; Denis Planchenault; Valéry Weber 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 286 KB

Kinetic investigations on the insertion of metal-carbenoid intermediates into the Si-H bond have been carried out. A kinetic isotope effect of 1.5 was found and the plot of log kx/krt vs cr for the reaction of arylsilanes with EDA, gave a straight line with p =-0.31. It was thus concluded that the i

Rhodium(II)-vinylcarbenoid insertion int

Rhodium(II)-vinylcarbenoid insertion into the SiH bond. A new stereospecific synthesis of allylsilanes

✍ Yannick Landais; Denis Planchenault; Valéry Weber 📂 Article 📅 1994 🏛 Elsevier Science 🌐 French ⚖ 327 KB

The insertion of diaryl carbenes into an

The insertion of diaryl carbenes into an imine NH bond

✍ K.N. Mehrotra; G. Prasad 📂 Article 📅 1978 🏛 Elsevier Science 🌐 French ⚖ 218 KB

Preparation and structures of mixed sili

Preparation and structures of mixed silicon-cobalt carbonyl clusters with SiH, SiO or SiS bonds

✍ Martin Van Tiel; Kenneth M. Mackay; Brian K. Nicholson 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 987 KB

Rhodium(II) (S)-N-(arylsulfonyl)prolinat

Rhodium(II) (S)-N-(arylsulfonyl)prolinate catalyzed asymmetric insertions of vinyl- and phenylcarbenoids into the SiH bond

✍ Huw M.L. Davies; Tore Hansen; James Rutberg; Paul R. Bruzinski 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 194 KB

Allylsilanes or benzylsilanes of high enantiomeric purity (77-95% ee) are formed from the rhodium(lI) (S)-N-[p-(dodecylphenyl)sulfonyl]prolinate (1) catalyzed decomposition of vinyldiazomethanes or phenyMiazomethanes in the presence of dimethylphenylsilane (3).