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Rhodium(II) (S)-N-(arylsulfonyl)prolinate catalyzed asymmetric insertions of vinyl- and phenylcarbenoids into the SiH bond

✍ Scribed by Huw M.L. Davies; Tore Hansen; James Rutberg; Paul R. Bruzinski

Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 194 KB
Volume: 38
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)00205-0

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✦ Synopsis

Allylsilanes or benzylsilanes of high enantiomeric purity (77-95% ee) are formed from the rhodium(lI) (S)-N-[p-(dodecylphenyl)sulfonyl]prolinate (1) catalyzed decomposition of vinyldiazomethanes or phenyMiazomethanes in the presence of dimethylphenylsilane (3).

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