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Rhodium(II)-vinylcarbenoid insertion into the SiH bond. A new stereospecific synthesis of allylsilanes

✍ Scribed by Yannick Landais; Denis Planchenault; Valéry Weber


Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
327 KB
Volume
35
Category
Article
ISSN
0040-4039

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Rhodium(II) (S)-N-(arylsulfonyl)prolinat
✍ Huw M.L. Davies; Tore Hansen; James Rutberg; Paul R. Bruzinski 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 194 KB

Allylsilanes or benzylsilanes of high enantiomeric purity (77-95% ee) are formed from the rhodium(lI) (S)-N-[p-(dodecylphenyl)sulfonyl]prolinate (1) catalyzed decomposition of vinyldiazomethanes or phenyMiazomethanes in the presence of dimethylphenylsilane (3).