Rhodium(II) (S)-N-(arylsulfonyl)prolinat
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Huw M.L. Davies; Tore Hansen; James Rutberg; Paul R. Bruzinski
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Article
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1997
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Elsevier Science
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French
⚖ 194 KB
Allylsilanes or benzylsilanes of high enantiomeric purity (77-95% ee) are formed from the rhodium(lI) (S)-N-[p-(dodecylphenyl)sulfonyl]prolinate (1) catalyzed decomposition of vinyldiazomethanes or phenyMiazomethanes in the presence of dimethylphenylsilane (3).