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The chemistry of phenalenium system XIV, 2,3-homophenalenone

โœ Scribed by Ichiro Murata; Kazuhiro Nakasuji

Book ID
104246936
Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
239 KB
Volume
14
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

The chemistry of the homoaromatic compounds is currently a topic of great interest. 2)

Although various studies for homotropones, 3) homotropylium ions 4)

๐Ÿ“œ SIMILAR VOLUMES

The chemistry of phenalenium systems. XX
The chemistry of phenalenium systems. XXV The triangulenyl dianion
โœ Osamu Hara; Katsuaki Tanaka; Kagetoshi Yamamoto; Tomoo Nakazawa; Ichiro Murata ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 136 KB

In 1953, Clar 2) suggested that so-called Clar's hydrocarbon, triangulene (I), would be impossible to prepare because no Kekule structure can be written for 1. Dehydrogenation of hexahydro-and dodecahydrotriangulene led in fact only to polymeric products. In terms of the valence

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The fulvalenes containing a phenalene fragment such as (1) are of interest because of their electronic characteristics distinct from the normal mixed fulvalenes (2).