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The chemistry of phenalenium system VIII generation and reactions of phenalenylidene

โœ Scribed by Ichiro Murata; Tomoo Nakazawa; Shuichi Yamamoto


Book ID
108384414
Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
229 KB
Volume
13
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES


The chemistry of phenalenium system XI 1
โœ Ichiro Murata; Tomoo Nakazawa; Taichi Imanishi ๐Ÿ“‚ Article ๐Ÿ“… 1972 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 206 KB

In the recent communication 2) we have described the generation and the reaction of phenalenylidene (2, a novel carbene species In which the divalent carbon center was incorporated with a phenalenyl conjugated system , and the triplet electronic ground state (3, has been suggested aa an Intermediate

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The chemistry of the homoaromatic compounds is currently a topic of great interest. 2) Although various studies for homotropones, 3) homotropylium ions 4)

The chemistry of phenalenium systems. XX
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In 1953, Clar 2) suggested that so-called Clar's hydrocarbon, triangulene (I), would be impossible to prepare because no Kekule structure can be written for 1. Dehydrogenation of hexahydro-and dodecahydrotriangulene led in fact only to polymeric products. In terms of the valence

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The fulvalenes containing a phenalene fragment such as (1) are of interest because of their electronic characteristics distinct from the normal mixed fulvalenes (2).