In the recent communication 2) we have described the generation and the reaction of phenalenylidene (2, a novel carbene species In which the divalent carbon center was incorporated with a phenalenyl conjugated system , and the triplet electronic ground state (3, has been suggested aa an Intermediate
The chemistry of phenalenium system VIII generation and reactions of phenalenylidene
โ Scribed by Ichiro Murata; Tomoo Nakazawa; Shuichi Yamamoto
- Book ID
- 108384414
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- French
- Weight
- 229 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The chemistry of the homoaromatic compounds is currently a topic of great interest. 2) Although various studies for homotropones, 3) homotropylium ions 4)
In 1953, Clar 2) suggested that so-called Clar's hydrocarbon, triangulene (I), would be impossible to prepare because no Kekule structure can be written for 1. Dehydrogenation of hexahydro-and dodecahydrotriangulene led in fact only to polymeric products. In terms of the valence
The fulvalenes containing a phenalene fragment such as (1) are of interest because of their electronic characteristics distinct from the normal mixed fulvalenes (2).