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The chemistry of phenalenium systems. XXV The triangulenyl dianion

โœ Scribed by Osamu Hara; Katsuaki Tanaka; Kagetoshi Yamamoto; Tomoo Nakazawa; Ichiro Murata


Book ID
104236046
Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
136 KB
Volume
18
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


In 1953, Clar 2) suggested that so-called Clar's hydrocarbon, triangulene (I), would be impossible to prepare because no Kekule structure can be written for 1. Dehydrogenation of hexahydro-and dodecahydrotriangulene led in fact only to polymeric products. In terms of the valence


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The chemistry of the homoaromatic compounds is currently a topic of great interest. 2) Although various studies for homotropones, 3) homotropylium ions 4)

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The fulvalenes containing a phenalene fragment such as (1) are of interest because of their electronic characteristics distinct from the normal mixed fulvalenes (2).