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The chemistry of phenalenium system XXII. on the question of 1,2- and 1,10-homoconjugation in the phenalenium ion.

✍ Scribed by Kazuhiro Nakasuji; Ichiro Murata


Book ID
108382146
Publisher
Elsevier Science
Year
1976
Tongue
French
Weight
228 KB
Volume
17
Category
Article
ISSN
0040-4039

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The chemistry of phenalenium system. XII
✍ Ichiro Murata; Kazuhiro Nakasuji πŸ“‚ Article πŸ“… 1973 πŸ› Elsevier Science 🌐 French βš– 230 KB

The most important synthesis of the valence isomer of benzenoid hydrocarbon, benzvalene (A) and naphthovalene (benzobenzvalene) (2) involves cyclization of the intermediate carbene species resulting from the cyclopentadienyl and/or the indenyl anlon with dichloromethane in the presence of alkyllithi