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The catalyst-forming reaction between trimethylaluminum and titanium trichloride

✍ Scribed by Rodriguez, L. ;Gabant, J.

Publisher: John Wiley and Sons
Year: 1962
Weight: 676 KB
Volume: 57
Category: Article
ISSN: 0022-3832
DOI: 10.1002/pol.1962.1205716569

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✦ Synopsis

Abstract

Experimental data and a reaction scheme concerning the reaction between TiCl~3~ and Al(CH~3~)~3~ are presented. The reaction yielding a polymerization‐active catalyst was studied in the absence of a solvent, predominantly at 65°C. The conclusion is drawn that about half of the carbon present on the catalyst is in the form of easily exchangeable CH~3~ groups.

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