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The reaction between triethylaluminum and titanium trichloride

✍ Scribed by Eden, C. ;Feilchenfeld, H.

Publisher
Wiley (John Wiley & Sons)
Year
1967
Tongue
English
Weight
82 KB
Volume
5
Category
Article
ISSN
0449-2986

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The catalyst-forming reaction between tr
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## Abstract Experimental data and a reaction scheme concerning the reaction between TiCl~3~ and Al(CH~3~)~3~ are presented. The reaction yielding a polymerization‐active catalyst was studied in the absence of a solvent, predominantly at 65°C. The conclusion is drawn that about half of the carbon pr

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## Abstract The dependence of uptake of Al(CH~3~)~3~ by solid TiCl~3~ on the surface area of the latter has been studied. A “step reaction” technique permits the investigation of the stoichiometry of the reaction at different degrees of advancement, the amount of chlorine abstracted from the TiCl~3

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## Abstract The influence of some typical oxygen‐, sulfur‐, and nitrogen‐containing impurties on the polymerization of propylene in a hydrocarbon medium under the catalytic action of titanium trichloride and triethylaluminum was studied. Both these catalyst components used in polar‐coordinated poly