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Stoichiometric considerations on the reaction between titanium trichloride and aluminum trimethyl

✍ Scribed by Mirella Miotto

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
808 KB
Volume
82
Category
Article
ISSN
0165-0513

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✦ Synopsis

Abstract

The dependence of uptake of Al(CH~3~)~3~ by solid TiCl~3~ on the surface area of the latter has been studied. A β€œstep reaction” technique permits the investigation of the stoichiometry of the reaction at different degrees of advancement, the amount of chlorine abstracted from the TiCl~3~ being taken as the advancement parameter.

Methane evolution and aluminum and carbon fixation on the solid phase appear to be linearly related to this parameter and the slopes of the respective lines are taken as significant parameters from which the stoichiometry of the reaction is deduced.

πŸ“œ SIMILAR VOLUMES

The catalyst-forming reaction between tr
The catalyst-forming reaction between trimethylaluminum and titanium trichloride
✍ Rodriguez, L. ;Gabant, J. πŸ“‚ Article πŸ“… 1962 πŸ› John Wiley and Sons βš– 676 KB

## Abstract Experimental data and a reaction scheme concerning the reaction between TiCl~3~ and Al(CH~3~)~3~ are presented. The reaction yielding a polymerization‐active catalyst was studied in the absence of a solvent, predominantly at 65Β°C. The conclusion is drawn that about half of the carbon pr