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The reaction between dicyclopentadienyl-dicarbonyl titanium and aryltin halides

✍ Scribed by Ji-Tao Wang; Yu-Ming Xu; Zhi-De Zhang

Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
324 KB
Volume
6
Category
Article
ISSN
1042-7163

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✦ Synopsis

The oxidation-elimination reaction between dicyclopentadienyl-dicarbonyl titanium, Cp,E(CO), fiis(methylcyclopentadieny1)dicarbonyl titanium, (MeCp),E(CO)J and aryltin halides was studied. Nineteen novel complexes containing the E-Sn bond were isolated. The reaction was proved to involve freeradical intemediates.

πŸ“œ SIMILAR VOLUMES

An ESR study on the reaction between dic
An ESR study on the reaction between dicarbonyl titanocene and aryl-tin halides
✍ Ling-Jun Bai; Zhi-De Zhang; Ji-Tao Wang πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 269 KB

The oxidation elimination reaction between dicar-bony1 titanocene and aryltin halides was studied by means of paramagnetic resonance spectroscopy. The radical intermediates containing E ( I I I ) were discovered from the ESR spectra to be (Cp,TiSnAr,J\_,,), Cp,E(CO)X, and Cp,EX, and a radical mechan