๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

An ESR study on the reaction between dicarbonyl titanocene and aryl-tin halides

โœ Scribed by Ling-Jun Bai; Zhi-De Zhang; Ji-Tao Wang

Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
269 KB
Volume
7
Category
Article
ISSN
1042-7163

No coin nor oath required. For personal study only.

โœฆ Synopsis

The oxidation elimination reaction between dicar-bony1 titanocene and aryltin halides was studied by means of paramagnetic resonance spectroscopy. The radical intermediates containing E ( I I I ) were discovered from the ESR spectra to be (Cp,TiSnAr,J_,,), Cp,E(CO)X, and Cp,EX, and a radical mechanism for the reaction is proposed.

๐Ÿ“œ SIMILAR VOLUMES

Kinetics of the reaction between alkalin
Kinetics of the reaction between alkaline sulfides and aryl dichlorides โ€” model study on 4-chloro- and 4,4โ€ฒ-dichlorobenzophenones
โœ Lotfi Hedhli; Christelle Lesclingant; Alain Fradet; Ernest Marรฉchal ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 790 KB

## Abstract The kinetics of the reaction between alkaline sulfides and halogenated aromatic monomers was studied using lithium sulfide and 4โ€chlorobenzophenone (1a) and 4,4โ€ฒโ€dichlorobenzophenone (1b) as models. The release of H~2~S from reaction medium and the possible formation of a compound betwe