The appearance energy of CF+3 from CF4: ion/molecule reactions related to the thermochemistry of CF+3
โ Scribed by Ellen R. Fisher; P.B. Armentrout
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 398 KB
- Volume
- 101
- Category
- Article
- ISSN
- 0168-1176
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An order of magnitude enhancement of the XeCl(B,C) formation rate constants was observed for the 300 K reactions of Xe( 6p[ l/2] 0 and [ 3/2]\*) atoms with CF&l, CF& and CF,HCl, relative to the reactions of Xe( 6s, 3P2) atoms. Similar large XeCl( B,C) formation enhancement factors were found for rea
A metastabie Ar beam was produced by electron impact with glow discharge. The A@P& beam intensity was estimated to be z I x 1 014 atoms sr-' s-'. Crossing this beam with a CF,H beam, collision-free emission of CF3 in the visible region was observed. The intensity maximum of the newly observed emiss