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Chemiluminescence of CF3 in the visible region from the crossed beam reaction of Ar(3P2,0) with CF3H

✍ Scribed by H. Ohoyama; T. Kasai; K. Ohashi; Y. Hirata; K. Kuwata

Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 354 KB
Volume: 131
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(86)80510-3

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✦ Synopsis

A metastabie Ar beam was produced by electron impact with glow discharge. The A@P& beam intensity was estimated to be z I x 1 014 atoms sr-' s-'. Crossing this beam with a CF,H beam, collision-free emission of CF3 in the visible region was observed.

The intensity maximum of the newly observed emission band of CF, was at 6 10 nm, different from a previously reported value of 565 nm from a flowing afterglow experiment. The cross section of the visible emission of CF3 was 5 1 A', i.e. 0.02 3~ 0.01 in terms of the branching fraction for the AI$~P& quenching.

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