Crossed beam study of the reaction of H+3 with D2
β Scribed by M.L. Vestal; C.R. Blakley; P.W. Ryan; J.H. Futrell
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- English
- Weight
- 301 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
The kinematics of the reaction H;(Dz, Hz)D~H+were studied over the initial relative energy range from 0.22 to 5.21 eV For ground state reactants. The reaction was found fo proceed via a direct mechanism at all energies studied. Indirect evidence suggests, however, that substantial comples formation may occur at energies below about 0.2 eV.
π SIMILAR VOLUMES
A crossed beam study of the title reaction if reported, from 0.45 to 7.8 eV. The reaction is predominantly transkxtioionally endothermic. At the lowest energy, there is evidence for two reactlon paths: a long-range electron transfer and an titimate coihsion mth electron transfer. Branching ratios fo
The doubly differential cross sections for the title reaction were measured in a crossed-beam apparatus. The product c.m. angular distributions were sharply backward but showed non-negligible contributions in the forward hemisphere. Contrary to conventional wisdom, these sideways/forward scatterings
Product energy and angular distributions have been measured for the exoergtc reaction O-+ CsH4 (alfene) + OH-+ C~H-J over the relative energy range 4.6-10 8 eV (65-15.3 eV lab) The reaction mechanism IS found to be direct and well-approuunated by the spectator-strrppmg modeL We see no evldeoce of ca
The angular and velocity distribution of the Cl0 product from the reaction O( 'D) + HCI at 12.2 kcal/mol collision energy has been obtained in a crossed-molecular-beam study. The product center-of-mass angular distribution is found to be almost backward-forward symmetric, with backward scattering be