✦ LIBER ✦

A crossed-beam study of the reaction of CN + D2. Is CN really a spectator bond?

✍ Scribed by Dock-Chil Che; Kopin Liu

Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 479 KB
Volume: 243
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(95)00859-3

No coin nor oath required. For personal study only.

✦ Synopsis

The doubly differential cross sections for the title reaction were measured in a crossed-beam apparatus. The product c.m. angular distributions were sharply backward but showed non-negligible contributions in the forward hemisphere. Contrary to conventional wisdom, these sideways/forward scatterings decrease with a slight increase in initial collision energies. In addition, their product translational energy distributions also displayed a strikingly sensitive dependence on the collision energies. Two possible scenarios were speculated. Both casted some doubts about the subtle role the CN radical played in this reaction as posed in the title.

📜 SIMILAR VOLUMES

A crossed molecular beam study of the ch

A crossed molecular beam study of the chemiluminescent reaction Xe(3P2,0) + BrCN → Xe(1S0) + Br + CN(B2Σ+)

✍ R.J. Hennessy; Yoko Ono; J.P. Simons 📂 Article 📅 1980 🏛 Elsevier Science 🌐 English ⚖ 448 KB

The c~ern~~~r~i~c~ce~t intcr~ction of Xef3i' energies ranging up to 70 kJ mol" z,e) artd BrC'N 1x1s been studicd under crossed-beam conditiorls et collision . The CNfR \* X) horuscencc spectrum, the excitation function for its production and the tluorcscence pnlnrisationor rather its absence \_ IWJC

A crossed beam study of the reaction C(3

A crossed beam study of the reaction C(3P) + N2O: energy partitioning between the NO(X 2Π) and CN(X 2Σ+) products

✍ S.A. Reid; F. Winterbottom; D.C. Scott; J. de Juan; H. Reisler 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 710 KB

A Crossed Molecular Beam Imaging Study o

A Crossed Molecular Beam Imaging Study of the O(1D2)+HCl→OH+Cl(2PJ=3/2, 1/2) Reaction

✍ Hiroshi Kohguchi; Toshinori Suzuki 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 349 KB

Chemical reaction kinematics—XVII crosse

Chemical reaction kinematics—XVII crossed beam study of the reaction CH+ +H2 → CH2+ +H

✍ G. Eisele; A. Henglein 📂 Article 📅 1975 🏛 Elsevier Science ⚖ 609 KB

A study of the reaction O + CS2 → SO + C

A study of the reaction O + CS2 → SO + CS using crossed molecular beams

✍ P.L. Moore; P.N. Clough; J. Geddes 📂 Article 📅 1972 🏛 Elsevier Science 🌐 English ⚖ 242 KB

A Crossed Molecular Beam Study on the Re

A Crossed Molecular Beam Study on the Reaction of Boron Atoms with Methylacetylene and Partially Deuterated Methylacetylene

✍ Fangtong Zhang; Chih Hao Kao; Agnes H. H. Chang; Xibin Gu; Ying Guo; Ralf I. Kai 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 866 KB