✦ LIBER ✦

Orientation dependence of chemiluminescence spectra of CF3 formed in the reaction of oriented CF3H with Ar(3P)

✍ Scribed by Hiroshi Ohoyama; Tomohiro Iguro; Toshio Kasai; Keiji Kuwata

Publisher: Elsevier Science
Year: 1993
Tongue: English
Weight: 533 KB
Volume: 209
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(93)80031-j

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✦ Synopsis

Chemiluminexence of the CQ radical formed in the reaction of Ar( 'P) with the oriented CFaH was taken at five different wavelengths in the range from 500 to 700 nm for two reactant orientations with a reference orientation. A remarkable alignment dependence of the emission spectra was observed. Analysis of the wavelength dependence of the CF, chemiluminescence revealed the existence of three reactive sites due to two reaction mechanisms. One is preferable at the side-on orientation and the second is both at the CF, end and H end orientations.

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