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Molecular beam reaction of K atoms with sideways oriented CF3I

โœ Scribed by Philip R. Brooks; John S. McKillop; H.Gary Pippin

Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
441 KB
Volume
66
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

Rrxctire scattering is obserrvd for K+CF31 -KI +CF3 where the CF31 is oriented "sideways" aith the I end pointing rur;lrds or asty from the detector_ Xnguhr distnbutions arc extremely broad and compIcteIy different from "heads" and %dlsw oricn~ations. Jlx.imum sigul corresponds to the '*torsards" oricntztion &ho-h r%.vSixity of fhe two orientations is .yuiKdcnt

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A variety of relative and absolute techniques have been used to measure the reactivity of fluorine atoms with a series of halogenated organic compounds and CO. The following rate constants were derived, in units of cm3 molecule-' s-l: CH3F, (3.7 2 0.8) X CH3C1, (3.3 2 0.71 X 10 -'I; CH3Br, (3.0 2 0.