The addition of dichlorocarbene to 3-methoxycyclohexene
β Scribed by Michael A. Tobias; Byron E. Johnston
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- French
- Weight
- 174 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0040-4039
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## Abstract A new product arising from the reaction of dichlorocarbene with norbornadiene, 6__endo__β(2,2βdichlorovinyl)β__cis__βbicyclo[3.1.0]hexβ2βene, is described. It does not arise from the normal __exo__βl,2βadduct, but possibly originates by sigmatropic rearrangement of an initially formed z
A recent reactivity comparison of dichlorocarbene and chlorofluorocarbene suggested that steric hindrance played an important role in determining the rate of the carbene-olefin addition reaction (1). Indeed, although warnings were is-